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Issue 13, 2014
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Iridium-catalyzed ortho-C–H borylation of aromatic aldimines derived from pentafluoroaniline with bis(pinacolate)diboron

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Abstract

The development of an Ir-catalyzed ortho-C–H borylation of aromatic aldimines derived from pentafluoroaniline is reported. This reaction proceeded at 120 °C to afford the corresponding borylated products in high yield with good regioselectivity using an Ir complex formed in situ from [Ir(OMe)(cod)]2/2(C6F5)3P in the presence of 2-norbornene.

Graphical abstract: Iridium-catalyzed ortho-C–H borylation of aromatic aldimines derived from pentafluoroaniline with bis(pinacolate)diboron

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Publication details

The article was received on 13 Dec 2013, accepted on 28 Jan 2014 and first published on 28 Jan 2014


Article type: Communication
DOI: 10.1039/C3OB42497A
Author version available: Download Author version (PDF)
Citation: Org. Biomol. Chem., 2014,12, 2041-2044
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    Iridium-catalyzed ortho-C–H borylation of aromatic aldimines derived from pentafluoroaniline with bis(pinacolate)diboron

    I. Sasaki, T. Amou, H. Ito and T. Ishiyama, Org. Biomol. Chem., 2014, 12, 2041
    DOI: 10.1039/C3OB42497A

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