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Issue 19, 2014
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Catalytic amounts of triarylaminium salt initiated aerobic oxidative coupling of N-aryl tetrahydroisoquinolines

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Abstract

A novel stable radical cation triarylaminium salt able to induce aerobic oxidative α-C–H functionalization of tertiary amines in catalytic amounts has been developed. The reaction is performed in the absence of any other additives under mild conditions and only requires atmosphere air as a sustainable co-oxidant.

Graphical abstract: Catalytic amounts of triarylaminium salt initiated aerobic oxidative coupling of N-aryl tetrahydroisoquinolines

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Publication details

The article was received on 09 Dec 2013, accepted on 11 Mar 2014 and first published on 12 Mar 2014


Article type: Paper
DOI: 10.1039/C3OB42454E
Citation: Org. Biomol. Chem., 2014,12, 3123-3128
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    Catalytic amounts of triarylaminium salt initiated aerobic oxidative coupling of N-aryl tetrahydroisoquinolines

    C. Huo, C. Wang, M. Wu, X. Jia, X. Wang, Y. Yuan and H. Xie, Org. Biomol. Chem., 2014, 12, 3123
    DOI: 10.1039/C3OB42454E

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