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Issue 8, 2014
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Huisgen-based conjugation of water-soluble porphyrins to deprotected sugars: towards mild strategies for the labelling of glycans

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Abstract

Fully deprotected alkynyl-functionalised mono- and oligosaccharides undergo CuAAC-based conjugation with water-soluble porphyrin azides in aqueous environments. The mild reaction conditions are fully compatible with the presence of labile glycosidic bonds. This approach provides an ideal strategy to conjugate tetrapyrroles to complex carbohydrates.

Graphical abstract: Huisgen-based conjugation of water-soluble porphyrins to deprotected sugars: towards mild strategies for the labelling of glycans

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Publication details

The article was received on 21 Nov 2013, accepted on 23 Dec 2013 and first published on 02 Jan 2014


Article type: Communication
DOI: 10.1039/C3OB42306A
Citation: Org. Biomol. Chem., 2014,12, 1203-1206
  • Open access: Creative Commons BY license
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    Huisgen-based conjugation of water-soluble porphyrins to deprotected sugars: towards mild strategies for the labelling of glycans

    F. Giuntini, F. Bryden, R. Daly, E. M. Scanlan and R. W. Boyle, Org. Biomol. Chem., 2014, 12, 1203
    DOI: 10.1039/C3OB42306A

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