Jump to main content
Jump to site search

Issue 13, 2014
Previous Article Next Article

Biomimetic aerobic oxidative hydroxylation of arylboronic acids to phenols catalysed by a flavin derivative

Author affiliations

Abstract

Flavin-catalysed oxidative hydroxylation of substituted arylboronic acids by molecular oxygen with the assistance of hydrazine or ascorbic acid resulted in phenols in high yields. This mild organocatalytic protocol is compatible with a variety of functional groups and it is alternatively usable for transformation of alkylboronic acids to alcohols. Reaction takes place also in water and fulfils criteria for a green procedure.

Graphical abstract: Biomimetic aerobic oxidative hydroxylation of arylboronic acids to phenols catalysed by a flavin derivative

Back to tab navigation

Supplementary files

Publication details

The article was received on 18 Oct 2013, accepted on 23 Jan 2014 and first published on 24 Jan 2014


Article type: Paper
DOI: 10.1039/C3OB42081G
Citation: Org. Biomol. Chem., 2014,12, 2137-2142
  • Open access: Creative Commons BY license
  •   Request permissions

    Biomimetic aerobic oxidative hydroxylation of arylboronic acids to phenols catalysed by a flavin derivative

    H. Kotoučová, I. Strnadová, M. Kovandová, J. Chudoba, H. Dvořáková and R. Cibulka, Org. Biomol. Chem., 2014, 12, 2137
    DOI: 10.1039/C3OB42081G

    This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
    • For reproduction of material from PCCP:
      [Original citation] - Published by the PCCP Owner Societies.
    • For reproduction of material from PPS:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
    • For reproduction of material from all other RSC journals:
      [Original citation] - Published by The Royal Society of Chemistry.

    Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Search articles by author

Spotlight

Advertisements