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Issue 13, 2014
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Biomimetic aerobic oxidative hydroxylation of arylboronic acids to phenols catalysed by a flavin derivative

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Abstract

Flavin-catalysed oxidative hydroxylation of substituted arylboronic acids by molecular oxygen with the assistance of hydrazine or ascorbic acid resulted in phenols in high yields. This mild organocatalytic protocol is compatible with a variety of functional groups and it is alternatively usable for transformation of alkylboronic acids to alcohols. Reaction takes place also in water and fulfils criteria for a green procedure.

Graphical abstract: Biomimetic aerobic oxidative hydroxylation of arylboronic acids to phenols catalysed by a flavin derivative

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Publication details

The article was received on 18 Oct 2013, accepted on 23 Jan 2014 and first published on 24 Jan 2014


Article type: Paper
DOI: 10.1039/C3OB42081G
Citation: Org. Biomol. Chem., 2014,12, 2137-2142
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    Biomimetic aerobic oxidative hydroxylation of arylboronic acids to phenols catalysed by a flavin derivative

    H. Kotoučová, I. Strnadová, M. Kovandová, J. Chudoba, H. Dvořáková and R. Cibulka, Org. Biomol. Chem., 2014, 12, 2137
    DOI: 10.1039/C3OB42081G

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