Issue 2, 2014
From the journal:

Organic & Biomolecular Chemistry

Rhodium-catalyzed intermolecular hydroarylation of internal alkynes with N-1-phenylbenzotriazoles†

Wang Zhou,*a   Youqing Yang,a   Zhiwei Wanga  and  Guo-Jun Dengb  

* Corresponding authors

a College of Chemical Engineering, Xiangtan University, Xiangtan 411105, China
E-mail: wzhou@xtu.edu.cn

b College of Chemistry, Xiangtan University, Xiangtan 411105, China

Abstract

A rhodium-catalyzed intermolecular hydroarylation of internal alkynes with N-1-phenylbenzotriazoles via C–H bond activation is described. This transformation offers an alternative method for the hydroarylation of internal alkynes with high stereoselectivity. The reaction mechanism was discussed according to the deuterium-labeling experiments.

Graphical abstract: Rhodium-catalyzed intermolecular hydroarylation of internal alkynes with N-1-phenylbenzotriazoles

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Article information

DOI
https://doi.org/10.1039/C3OB42007H
Article type
Communication
Submitted
05 Oct 2013
Accepted
05 Nov 2013
First published
07 Nov 2013

Org. Biomol. Chem., 2014,12, 251-254

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Rhodium-catalyzed intermolecular hydroarylation of internal alkynes with N-1-phenylbenzotriazoles

W. Zhou, Y. Yang, Z. Wang and G. Deng, Org. Biomol. Chem., 2014, 12, 251 DOI: 10.1039/C3OB42007H

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