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Issue 5, 2014
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DABCO catalyzed cross-Rauhut–Currier/transesterification reactions of activated alkenes with phenyl acrylates: scope and mechanistic insight

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Abstract

DABCO catalyzed the cross-Rauhut–Currier/transesterification reaction of α-cyano-α,β-unsaturated ketones and aryl acrylates was discovered. The reaction rate law was determined by an integral method under pseudo-first-order reaction conditions, which assisted in proposing the mechanism of cross-Rauhut–Currier reaction promoted by Brønsted acid and establishing the rate-determining step.

Graphical abstract: DABCO catalyzed cross-Rauhut–Currier/transesterification reactions of activated alkenes with phenyl acrylates: scope and mechanistic insight

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Publication details

The article was received on 29 Aug 2013, accepted on 06 Nov 2013 and first published on 06 Nov 2013


Article type: Paper
DOI: 10.1039/C3OB41763H
Citation: Org. Biomol. Chem., 2014,12, 832-835
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    DABCO catalyzed cross-Rauhut–Currier/transesterification reactions of activated alkenes with phenyl acrylates: scope and mechanistic insight

    W. Liu and G. Zhao, Org. Biomol. Chem., 2014, 12, 832
    DOI: 10.1039/C3OB41763H

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