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Issue 17, 2014
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Nanoalloying bulk-immiscible iridium and palladium inhibits hydride formation and promotes catalytic performances

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Abstract

The hydrogen sorption properties of oxide-supported Ir–Pd nanoalloys have been determined for the first time, and correlated with their catalytic behavior. The addition of Ir to Pd suppresses hydride formation and leads to improved catalytic performances with respect to pure metals in the preferential oxidation of CO in H2 excess (PROX).

Graphical abstract: Nanoalloying bulk-immiscible iridium and palladium inhibits hydride formation and promotes catalytic performances

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Publication details

The article was received on 23 May 2014, accepted on 24 Jun 2014 and first published on 26 Jun 2014


Article type: Communication
DOI: 10.1039/C4NR02836H
Author version available: Download Author version (PDF)
Citation: Nanoscale, 2014,6, 9955-9959
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    Nanoalloying bulk-immiscible iridium and palladium inhibits hydride formation and promotes catalytic performances

    C. Zlotea, F. Morfin, T. S. Nguyen, N. T. Nguyen, J. Nelayah, C. Ricolleau, M. Latroche and L. Piccolo, Nanoscale, 2014, 6, 9955
    DOI: 10.1039/C4NR02836H

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