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Issue 4, 2014
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Aerobic oxidation of isosorbide and isomannide employing TEMPO/laccase

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Abstract

The oxidation of the renewable diols isosorbide and isomannide was successfully achieved using a TEMPO/laccase system. Furthermore, various TEMPO-derivatives were tested leading to conversions of up to >99% for the oxidation of isosorbide, isomannide, indanol and a halohydrin to the corresponding ketone.

Graphical abstract: Aerobic oxidation of isosorbide and isomannide employing TEMPO/laccase

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Publication details

The article was received on 05 Sep 2013, accepted on 22 Jan 2014 and first published on 30 Jan 2014


Article type: Communication
DOI: 10.1039/C3GC41855C
Citation: Green Chem., 2014,16, 2117-2121
  • Open access: Creative Commons BY license
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    Aerobic oxidation of isosorbide and isomannide employing TEMPO/laccase

    J. Gross, K. Tauber, M. Fuchs, N. G. Schmidt, A. Rajagopalan, K. Faber, W. M. F. Fabian, J. Pfeffer, T. Haas and W. Kroutil, Green Chem., 2014, 16, 2117
    DOI: 10.1039/C3GC41855C

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