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Volume 171, 2014
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Analysis of a measurement scheme for ultrafast hole dynamics by few femtosecond resolution X-ray pump–probe Auger spectroscopy

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Abstract

Ultrafast hole dynamics created in molecular systems as a result of sudden ionisation is the focus of much attention in the field of attosecond science. Using the molecule glycine we show through ab initio simulations that the dynamics of a hole, arising from ionisation in the inner valence region, evolves with a timescale appropriate to be measured using X-ray pulses from the current generation of SASE free electron lasers. The examined pump–probe scheme uses X-rays with photon energy below the K edge of carbon (275–280 eV) that will ionise from the inner valence region. A second probe X-ray at the same energy can excite an electron from the core to fill the vacancy in the inner-valence region. The dynamics of the inner valence hole can be tracked by measuring the Auger electrons produced by the subsequent refilling of the core hole as a function of pump–probe delay. We consider the feasibility of the experiment and include numerical simulation to support this analysis. We discuss the potential for all X-ray pump-X-ray probe Auger spectroscopy measurements for tracking hole migration.

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Publication details

The article was received on 25 Mar 2014, accepted on 30 Apr 2014 and first published on 30 Apr 2014


Article type: Paper
DOI: 10.1039/C4FD00051J
Author version available: Download Author version (PDF)
Citation: Faraday Discuss., 2014,171, 93-111
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    Analysis of a measurement scheme for ultrafast hole dynamics by few femtosecond resolution X-ray pump–probe Auger spectroscopy

    B. Cooper, P. Kolorenč, L. J. Frasinski, V. Averbukh and J. P. Marangos, Faraday Discuss., 2014, 171, 93
    DOI: 10.1039/C4FD00051J

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