Issue 4, 2015

Metal-induced B–H bond activation: reactions between half-sandwich Ir and Rh complexes with carboranylthioamide

Abstract

Novel half-sandwich metal (Ir, Rh) complexes constructed from carboranylthioamide ligands containing an unexpected metal–boron bond were synthesized and characterized. The strong base n-butyllithium is demonstrated to be necessary in the reaction process.

Graphical abstract: Metal-induced B–H bond activation: reactions between half-sandwich Ir and Rh complexes with carboranylthioamide

Supplementary files

Article information

Article type
Communication
Submitted
26 Nov 2014
Accepted
28 Nov 2014
First published
28 Nov 2014

Dalton Trans., 2015,44, 1530-1533

Author version available

Metal-induced B–H bond activation: reactions between half-sandwich Ir and Rh complexes with carboranylthioamide

B. Xu, Y. Wang, Z. Yao and G. Jin, Dalton Trans., 2015, 44, 1530 DOI: 10.1039/C4DT03624G

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