Issue 2, 2015

3D Co(ii) coordination polymer with ferrimagnetic-like layers based on azide and tetrazolate bridges showing slow magnetic dynamics

Abstract

A novel 3D Co(II) coordination polymer, [Co6(4-ptz)6(N3)6]n (1) (4-ptz = 4-(pyridinyl)tetrazole), was synthesized by in situ hydrothermal reaction and characterized magnetically. Compound 1 consists of ferrimagnetic-like Co(II) layers with the title heterobridges and exhibits the spin-glass slow dynamics. The study on spin-glass behavior in mixed azide and tetrazolate bridged compounds is the first example.

Graphical abstract: 3D Co(ii) coordination polymer with ferrimagnetic-like layers based on azide and tetrazolate bridges showing slow magnetic dynamics

Supplementary files

Article information

Article type
Communication
Submitted
29 Oct 2014
Accepted
20 Nov 2014
First published
21 Nov 2014

Dalton Trans., 2015,44, 511-514

3D Co(II) coordination polymer with ferrimagnetic-like layers based on azide and tetrazolate bridges showing slow magnetic dynamics

X. Zhang, P. Li, W. Gao, J. Liu and E. Gao, Dalton Trans., 2015, 44, 511 DOI: 10.1039/C4DT03332A

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