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Issue 39, 2014
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Direct synthesis of the Janus-head ligand (MePy)3Sn–Sn(MePy)3 using an unusual pyridyl-transfer reaction (MePy = 6-methyl-2-pyridyl)

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Abstract

The in situ reaction of the tripodal anion [EtAl(MePy)3] (MePy = 6-Me-2-py) with SnCl2 gives the Janus-head ligand (MePy)3Sn–Sn(MePy)3, containing a Sn–Sn bond, through a novel, one-pot reaction involving a combination of pyridyl transfer and metal-oxidation.

Graphical abstract: Direct synthesis of the Janus-head ligand (MePy)3Sn–Sn(MePy)3 using an unusual pyridyl-transfer reaction (MePy = 6-methyl-2-pyridyl)

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Publication details

The article was received on 19 Jun 2014, accepted on 29 Jul 2014 and first published on 06 Aug 2014


Article type: Communication
DOI: 10.1039/C4DT02216E
Citation: Dalton Trans., 2014,43, 14529-14532
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    Direct synthesis of the Janus-head ligand (MePy)3Sn–Sn(MePy)3 using an unusual pyridyl-transfer reaction (MePy = 6-methyl-2-pyridyl)

    R. García-Rodríguez and D. S. Wright, Dalton Trans., 2014, 43, 14529
    DOI: 10.1039/C4DT02216E

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