Issue 39, 2014

Multifunctional MOFs through CO2 fixation: a metamagnetic kagome lattice with uniaxial zero thermal expansion and reversible guest sorption

Abstract

The properties of atmospheric CO2 fixation, metamagnetism, reversible guest adsorption and zero thermal expansion have been combined in a single robust MOF, [Cu3(bpac)3(CO3)2](ClO4)2·H2O (1·H2O). This compound is a ditopically-bridged copper carbonate kagome lattice where desolvation of the MOF allows subtle tuning of the metamagnetic and uniaxial ZTE behaviour.

Graphical abstract: Multifunctional MOFs through CO2 fixation: a metamagnetic kagome lattice with uniaxial zero thermal expansion and reversible guest sorption

Supplementary files

Article information

Article type
Paper
Submitted
21 Jul 2014
Accepted
25 Jul 2014
First published
22 Aug 2014

Dalton Trans., 2014,43, 14766-14771

Author version available

Multifunctional MOFs through CO2 fixation: a metamagnetic kagome lattice with uniaxial zero thermal expansion and reversible guest sorption

T. D. Keene, M. J. Murphy, J. R. Price, N. F. Sciortino, P. D. Southon and C. J. Kepert, Dalton Trans., 2014, 43, 14766 DOI: 10.1039/C4DT02205J

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