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Issue 39, 2014
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Unexpected metal ion-assisted transformations leading to unexplored bridging ligands in NiII coordination chemistry: the case of PO3F2− group

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Abstract

The initial ‘accidental’, metal ion-assisted hydrolysis of PF6 to PO3F2− has been evolved in a systematic investigation of the bridging affinity of the latter group in NiII/oximate chemistry; mono-, di- and trinuclear complexes have been prepared and confirmed both the rich reactivity of PO3F2− and its potential for further use as bridging ligand in high-nuclearity 3d-metal cluster chemistry.

Graphical abstract: Unexpected metal ion-assisted transformations leading to unexplored bridging ligands in NiII coordination chemistry: the case of PO3F2− group

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Publication details

The article was received on 21 Jul 2014, accepted on 13 Aug 2014 and first published on 14 Aug 2014


Article type: Communication
DOI: 10.1039/C4DT02204A
Citation: Dalton Trans., 2014,43, 14520-14524
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    Unexpected metal ion-assisted transformations leading to unexplored bridging ligands in NiII coordination chemistry: the case of PO3F2− group

    D. Dermitzaki, C. P. Raptopoulou, V. Psycharis, A. Escuer, S. P. Perlepes and T. C. Stamatatos, Dalton Trans., 2014, 43, 14520
    DOI: 10.1039/C4DT02204A

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