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Issue 36, 2014
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2-Quinoxalinol diamine Cu(II) complex: facilitating catalytic oxidation through dual mechanisms

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Abstract

The Cu(II) complex 1, Cu(II)-6-N-3,5-di-tert-butylsalicylidene-6,7-quinoxalinol-diamine, has been developed to address problems with current methods of catalytic oxidation using tert-butyl hydroperoxide (TBHP). Complex 1 demonstrated an increased capability to utilize TBHP while limiting interference from free radical reactions and was demonstrated to be highly effective in the oxidations of a variety of olefins.

Graphical abstract: 2-Quinoxalinol diamine Cu(ii) complex: facilitating catalytic oxidation through dual mechanisms

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Publication details

The article was received on 05 Jun 2014, accepted on 27 Jul 2014 and first published on 28 Jul 2014


Article type: Paper
DOI: 10.1039/C4DT01562B
Citation: Dalton Trans., 2014,43, 13578-13583
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    2-Quinoxalinol diamine Cu(II) complex: facilitating catalytic oxidation through dual mechanisms

    Y. Li, T. Lee, K. Weerasiri, T. Wang, E. E. Buss, M. L. McKee and A. E. V. Gorden, Dalton Trans., 2014, 43, 13578
    DOI: 10.1039/C4DT01562B

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