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DFT examination of rare α-SiMe3 abstraction in Ta(NMe2)4[N(SiMe3)2]: formation of the imide compound Ta([double bond, length as m-dash]NSiMe3)(NMe2)3 and its trapping to give guanidinate imides

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a
Department of Chemistry, The University of North Texas, Denton, USA
E-mail: cobalt@unt.edu ;
Tel: +1 940-565-3548
b
Department of Chemistry, The University of Tennessee, Knoxville, USA
Dalton Trans., 2014,43, 12390-12395

DOI: 10.1039/C4DT01521E
Received 23 May 2014, Accepted 20 Jun 2014
First published online 20 Jun 2014
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