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Paper

Si–H bond activation at {(NHC)2Ni0} leading to hydrido silyl and bis(silyl) complexes: a versatile tool for catalytic Si–H/D exchange, acceptorless dehydrogenative coupling of hydrosilanes, and hydrogenation of disilanes to hydrosilanes

David Schmidt,a   Thomas Zell,b   Thomas Schaubc and   Udo Radius*a  
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Corresponding authors
a
Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany
E-mail: u.radius@uni-wuerzburg.de
b
Department of Organic Chemistry, Weizmann Institute of Science, 76100 Rehovot, Israel
c
BASF SE, GCS/H-M313, 67056 Ludwigshafen, Germany
Dalton Trans., 2014,43, 10816-10827

DOI: 10.1039/C4DT01250J
Received 28 Apr 2014, Accepted 06 May 2014
First published online 06 May 2014
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