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Issue 36, 2014
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Ammonium- and phosphonium-based temperature control-type polyoxometalate ionic liquids

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Abstract

Ammonium- and phosphonium-based polyoxometalate ionic liquids (POM-ILs) have been synthesized and characterized. The results of small-angle XRD indicate that phosphonium-based POM-IL possesses a layered type structure. They are temperature control-type POM-ILs and can exhibit a phase transformation below 100 °C. Phosphonium-based POM-IL exhibits higher thermal stability and conductivity than its ammonium analogue.

Graphical abstract: Ammonium- and phosphonium-based temperature control-type polyoxometalate ionic liquids

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Publication details

The article was received on 18 Apr 2014, accepted on 18 Jul 2014 and first published on 06 Aug 2014


Article type: Paper
DOI: 10.1039/C4DT01146E
Citation: Dalton Trans., 2014,43, 13591-13595
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    Ammonium- and phosphonium-based temperature control-type polyoxometalate ionic liquids

    Y. Li, X. Wu, Q. Wu, H. Ding and W. Yan, Dalton Trans., 2014, 43, 13591
    DOI: 10.1039/C4DT01146E

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