Issue 36, 2014

Ammonium- and phosphonium-based temperature control-type polyoxometalate ionic liquids

Abstract

Ammonium- and phosphonium-based polyoxometalate ionic liquids (POM-ILs) have been synthesized and characterized. The results of small-angle XRD indicate that phosphonium-based POM-IL possesses a layered type structure. They are temperature control-type POM-ILs and can exhibit a phase transformation below 100 °C. Phosphonium-based POM-IL exhibits higher thermal stability and conductivity than its ammonium analogue.

Graphical abstract: Ammonium- and phosphonium-based temperature control-type polyoxometalate ionic liquids

Article information

Article type
Paper
Submitted
18 Apr 2014
Accepted
18 Jul 2014
First published
06 Aug 2014

Dalton Trans., 2014,43, 13591-13595

Author version available

Ammonium- and phosphonium-based temperature control-type polyoxometalate ionic liquids

Y. Li, X. Wu, Q. Wu, H. Ding and W. Yan, Dalton Trans., 2014, 43, 13591 DOI: 10.1039/C4DT01146E

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