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Issue 24, 2014
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Synthesis and electronic structure of the first cyaphide-alkynyl complexes

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Abstract

The novel complexes trans-[Ru(dppe)2(C[triple bond, length as m-dash]CR)(C[triple bond, length as m-dash]P)] (R = CO2Me, C6H4OMe), the first to incorporate cyaphide as part of a conjugated system, are obtained in facile manner. The electronic structure of these compounds is probed by X-ray, DFT and UV/Vis studies.

Graphical abstract: Synthesis and electronic structure of the first cyaphide-alkynyl complexes

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Publication details

The article was received on 14 Apr 2014, accepted on 22 Apr 2014 and first published on 24 Apr 2014


Article type: Communication
DOI: 10.1039/C4DT01108B
Author version available: Download Author version (PDF)
Citation: Dalton Trans., 2014,43, 9004-9007
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    Synthesis and electronic structure of the first cyaphide-alkynyl complexes

    N. Trathen, M. C. Leech, I. R. Crossley, V. K. Greenacre and S. M. Roe, Dalton Trans., 2014, 43, 9004
    DOI: 10.1039/C4DT01108B

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