Jump to main content
Jump to site search

Issue 23, 2014
Previous Article Next Article

Pincer versus pseudopincer: isomerism in palladium(II) complexes bearing κ3C,S,C ligands

Author affiliations

Abstract

In NHC pincer complexes incorporating a hemilabile donor site, there exists an equilibrium between the true pincer form and a pseudopincer coordination isomer. The influence of the NHC moieties on this isomerism has been studied by DFT calculations.

Graphical abstract: Pincer versus pseudopincer: isomerism in palladium(ii) complexes bearing κ3C,S,C ligands

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 09 Apr 2014, accepted on 14 Apr 2014 and first published on 14 Apr 2014


Article type: Communication
DOI: 10.1039/C4DT01047G
Citation: Dalton Trans., 2014,43, 8591-8594
  • Open access: Creative Commons BY license
  •   Request permissions

    Pincer versus pseudopincer: isomerism in palladium(II) complexes bearing κ3C,S,C ligands

    J. C. Bernhammer, G. Frison and H. V. Huynh, Dalton Trans., 2014, 43, 8591
    DOI: 10.1039/C4DT01047G

    This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
    • For reproduction of material from PCCP:
      [Original citation] - Published by the PCCP Owner Societies.
    • For reproduction of material from PPS:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
    • For reproduction of material from all other RSC journals:
      [Original citation] - Published by The Royal Society of Chemistry.

    Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Search articles by author