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Issue 32, 2014
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Chemical tuning of the magnetic relaxation in dysprosium(III) mononuclear complexes

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Abstract

A dysprosium(III) complex, exhibiting slow relaxation of magnetization, was prepared. Crystallographic studies showed a perturbation of local symmetry upon deprotonation of the ligand, with concomitant faster relaxation of magnetization. This was attributed to a large shift in the direction of the main magnetic axis, as indicated by ab initio calculations.

Graphical abstract: Chemical tuning of the magnetic relaxation in dysprosium(iii) mononuclear complexes

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Publication details

The article was received on 21 Mar 2014, accepted on 01 May 2014 and first published on 02 May 2014


Article type: Communication
DOI: 10.1039/C4DT00846D
Citation: Dalton Trans., 2014,43, 12146-12149
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    Chemical tuning of the magnetic relaxation in dysprosium(III) mononuclear complexes

    L. J. Batchelor, I. Cimatti, R. Guillot, F. Tuna, W. Wernsdorfer, L. Ungur, L. F. Chibotaru, V. E. Campbell and T. Mallah, Dalton Trans., 2014, 43, 12146
    DOI: 10.1039/C4DT00846D

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