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Issue 30, 2014
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Magnetic anisotropy in a spin 1/2 quasi-one-dimensional antiferromagnetic copper(II) complex CuCl2(pdz) with a staggered g-tensor

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Abstract

We report an unusual magnetic anisotropy in a S = 1/2 1D antiferromagnetic (AF) compound CuCl2(pdz) (pdz = pyridazine). The magnetic susceptibility for H//a* and H//c showed characteristic behavior in the S = 1/2 1D Heisenberg AF system, whereas that for H//b exhibited a 1/T contribution. The origin of such an anomalous anisotropy in the magnetic susceptibility is explained by the staggered g-tensor of this compound.

Graphical abstract: Magnetic anisotropy in a spin 1/2 quasi-one-dimensional antiferromagnetic copper(ii) complex CuCl2(pdz) with a staggered g-tensor

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Publication details

The article was received on 18 Mar 2014, accepted on 12 Apr 2014 and first published on 14 Apr 2014


Article type: Paper
DOI: 10.1039/C4DT00809J
Citation: Dalton Trans., 2014,43, 11529-11532
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    Magnetic anisotropy in a spin 1/2 quasi-one-dimensional antiferromagnetic copper(II) complex CuCl2(pdz) with a staggered g-tensor

    S. Takaishi, H. Kitagawa, H. Tanaka, S. Kuroda and R. Ikeda, Dalton Trans., 2014, 43, 11529
    DOI: 10.1039/C4DT00809J

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