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Issue 33, 2014
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Novel iodinated carboranes: synthesis of the 8-iodo-7,9-dicarba-nido-undecaborate anion and 2-iodo-1,7-dicarba-closo-dodecaborane

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Abstract

Electrophilic iodination of the 7,9-dicarba-nido-undecaborate anion with molecular iodine in the presence of AlCl3 generated a new carborane anion—8-iodo-7,9-dicarba-nido-undecaborate—in excellent yield. The capping of the new anion with HBCl2 yielded a previously unknown neutral iodinated carborane, 2-iodo-1,7-dicarba-closo-dodecaborane.

Graphical abstract: Novel iodinated carboranes: synthesis of the 8-iodo-7,9-dicarba-nido-undecaborate anion and 2-iodo-1,7-dicarba-closo-dodecaborane

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Publication details

The article was received on 13 Mar 2014, accepted on 22 Apr 2014 and first published on 23 Apr 2014


Article type: Communication
DOI: 10.1039/C4DT00764F
Citation: Dalton Trans., 2014,43, 12467-12469
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    Novel iodinated carboranes: synthesis of the 8-iodo-7,9-dicarba-nido-undecaborate anion and 2-iodo-1,7-dicarba-closo-dodecaborane

    A. V. Safronov, K. Z. Kabytaev, S. S. Jalisatgi and M. F. Hawthorne, Dalton Trans., 2014, 43, 12467
    DOI: 10.1039/C4DT00764F

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