Issue 33, 2014
From the journal:

Dalton Transactions

Novel iodinated carboranes: synthesis of the 8-iodo-7,9-dicarba-nido-undecaborate anion and 2-iodo-1,7-dicarba-closo-dodecaborane†

Alexander V. Safronov,a   Kuanysh Z. Kabytaev,a   Satish S. Jalisatgia  and  M. Frederick Hawthorne*a  

* Corresponding authors

a International Institute of Nano and Molecular Medicine, School of Medicine, University of Missouri-Columbia, 1514 Research Park Drive, Columbia, MO 65211, USA
E-mail: hawthornem@missouri.edu

Abstract

Electrophilic iodination of the 7,9-dicarba-nido-undecaborate anion with molecular iodine in the presence of AlCl3 generated a new carborane anion—8-iodo-7,9-dicarba-nido-undecaborate—in excellent yield. The capping of the new anion with HBCl2 yielded a previously unknown neutral iodinated carborane, 2-iodo-1,7-dicarba-closo-dodecaborane.

Graphical abstract: Novel iodinated carboranes: synthesis of the 8-iodo-7,9-dicarba-nido-undecaborate anion and 2-iodo-1,7-dicarba-closo-dodecaborane

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Article information

DOI
https://doi.org/10.1039/C4DT00764F
Article type
Communication
Submitted
13 Mar 2014
Accepted
22 Apr 2014
First published
23 Apr 2014

Dalton Trans., 2014,43, 12467-12469

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Novel iodinated carboranes: synthesis of the 8-iodo-7,9-dicarba-nido-undecaborate anion and 2-iodo-1,7-dicarba-closo-dodecaborane

A. V. Safronov, K. Z. Kabytaev, S. S. Jalisatgi and M. F. Hawthorne, Dalton Trans., 2014, 43, 12467 DOI: 10.1039/C4DT00764F

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