Exploration of the slow relaxation behavior in the manganese phosphate network

Bo Li; Ning Jiang; Jumei Tian; Tingting Li; Guixiang Hou; Jingping Zhang

doi:10.1039/C4DT00703D

Exploration of the slow relaxation behavior in the manganese phosphate network

Bo Li,^a^b Ning Jiang,^a Jumei Tian,^b Tingting Li,^a Guixiang Hou^a and Jingping Zhang*^b

* Corresponding authors

^a Hebei Provincial Key Laboratory of Inorganic Nonmetallic Materials, College of Materials Science and Engineering; College of Public Health, Hebei United University, Tangshan 063009, China

^b Faculty of Chemistry, Northeast Normal University, Changchun 130024, China
E-mail: jpzhang@nenu.edu.cn

Abstract

Our endeavors are devoted to the explanation of the nature of the magnetic relaxation phenomena in the herein prepared [Mn^II₅(HPO₄)₂(PO₄)₂(H₂O)₄]_n (1). The behavior investigation indicates the prominence of the half-occupied magnetic centers and the competence of the antiferromagnetic interactions and non-zero magnetic moments. The investigation suggests that the design and synthesis of unusual magnetic center materials with innate unquenched magnetic moments could provide a new route for the production of molecular magnets with magnetic relaxation.

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Publication details

The article was received on 19 Mar 2014, accepted on 27 Mar 2014 and first published on 27 Mar 2014

Article type: Paper

DOI: 10.1039/C4DT00703D

Author version available: Download Author version (PDF)

Citation: Dalton Trans., 2014,43, 9267-9270

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Exploration of the slow relaxation behavior in the manganese phosphate network

B. Li, N. Jiang, J. Tian, T. Li, G. Hou and J. Zhang, Dalton Trans., 2014, 43, 9267
DOI: 10.1039/C4DT00703D
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Dalton Transactions

Exploration of the slow relaxation behavior in the manganese phosphate network

Abstract

Supplementary files

Publication details

Exploration of the slow relaxation behavior in the manganese phosphate network

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