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Issue 19, 2014
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Redox-active phosphines: synthesis and crystal structures of palladium(II) complexes of a metallaphosphine in two different oxidation states

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Abstract

The redox-active metallaphosphine [Fe(dppe)(η5-C5Me5)(C[triple bond, length as m-dash]C–PPh2)] reacts with [Pd(1,5-cod)Cl2] to give mono- and bis-phosphine coordinated palladium centres as a function of stoichiometry, and these complexes provide a stable redox-active platform which allows reversible one-electron {Fe(II)→Fe(III)+} oxidations within the palladium coordination sphere.

Graphical abstract: Redox-active phosphines: synthesis and crystal structures of palladium(ii) complexes of a metallaphosphine in two different oxidation states

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Publication details

The article was received on 12 Feb 2014, accepted on 18 Feb 2014 and first published on 07 Apr 2014


Article type: Communication
DOI: 10.1039/C4DT00455H
Citation: Dalton Trans., 2014,43, 7002-7005
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    Redox-active phosphines: synthesis and crystal structures of palladium(II) complexes of a metallaphosphine in two different oxidation states

    A. Tohmé, S. Labouille, T. Roisnel, V. Dorcet, D. Carmichael and F. Paul, Dalton Trans., 2014, 43, 7002
    DOI: 10.1039/C4DT00455H

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