Issue 19, 2014
From the journal:

Dalton Transactions

Redox-active phosphines: synthesis and crystal structures of palladium(ii) complexes of a metallaphosphine in two different oxidation states†

Ayham Tohmé,a   Stéphanie Labouille,b   Thierry Roisnel,a   Vincent Dorcet,a   Duncan Carmichael*b  and  Frédéric Paul*a  

* Corresponding authors

a Institut des Sciences Chimiques de Rennes, CNRS (UMR 6226) Université de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex, France
E-mail: frederic.paul@univ-rennes1.fr
Fax: +(033)223236939

b Laboratoire Hétéroéléments et Coordination, CNRS (UMR 7653), Ecole Polytechnique, 91128 Palaiseau Cedex, France
E-mail: duncan.carmichael@polytechnique.edu
Fax: +(033)169334440

Abstract

The redox-active metallaphosphine [Fe(dppe)(η5-C5Me5)(C[triple bond, length as m-dash]C–PPh2)] reacts with [Pd(1,5-cod)Cl2] to give mono- and bis-phosphine coordinated palladium centres as a function of stoichiometry, and these complexes provide a stable redox-active platform which allows reversible one-electron {Fe(II)→Fe(III)+} oxidations within the palladium coordination sphere.

Graphical abstract: Redox-active phosphines: synthesis and crystal structures of palladium(ii) complexes of a metallaphosphine in two different oxidation states

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Article information

DOI
https://doi.org/10.1039/C4DT00455H
Article type
Communication
Submitted
12 Feb 2014
Accepted
18 Feb 2014
First published
07 Apr 2014

Dalton Trans., 2014,43, 7002-7005

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Redox-active phosphines: synthesis and crystal structures of palladium(II) complexes of a metallaphosphine in two different oxidation states

A. Tohmé, S. Labouille, T. Roisnel, V. Dorcet, D. Carmichael and F. Paul, Dalton Trans., 2014, 43, 7002 DOI: 10.1039/C4DT00455H

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