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Issue 17, 2014
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A hybrid vanadium fluoride with structurally isolated S = 1 kagome layers

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Abstract

A new organically-templated vanadium(III) fluoride, (NH4)2(C2H8N)[V3F12], has been prepared using an ionothermal approach. This compound has a unique layered structure featuring distorted S = 1 kagome planes separated by the cationic species. The compound exhibits magnetic frustration, with a canted antiferromagnetic ground state. On further cooling in the ground state a pronounced change in magnetisation kinetics is observed.

Graphical abstract: A hybrid vanadium fluoride with structurally isolated S = 1 kagome layers

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Publication details

The article was received on 12 Feb 2014, accepted on 13 Feb 2014 and first published on 13 Feb 2014


Article type: Communication
DOI: 10.1039/C4DT00452C
Citation: Dalton Trans., 2014,43, 6304-6307
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    A hybrid vanadium fluoride with structurally isolated S = 1 kagome layers

    F. H. Aidoudi, L. J. Downie, R. E. Morris, M. A. de Vries and P. Lightfoot, Dalton Trans., 2014, 43, 6304
    DOI: 10.1039/C4DT00452C

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