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Issue 20, 2014
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Thioether-ligated iron(II) and iron(III)-hydroperoxo/alkylperoxo complexes with an H-bond donor in the second coordination sphere

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Abstract

The non-heme iron complexes, [FeII(N3PySR)(CH3CN)](BF4)2 (1) and [FeII(N3PyamideSR)](BF4)2 (2), afford rare examples of metastable Fe(III)-OOH and Fe(III)-OOtBu complexes containing equatorial thioether ligands and a single H-bond donor in the second coordination sphere. These peroxo complexes were characterized by a range of spectroscopic methods and density functional theory studies. The influence of a thioether ligand and of one H-bond donor on the stability and spectroscopic properties of these complexes was investigated.

Graphical abstract: Thioether-ligated iron(ii) and iron(iii)-hydroperoxo/alkylperoxo complexes with an H-bond donor in the second coordination sphere

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Publication details

The article was received on 25 Jan 2014, accepted on 26 Mar 2014, published on 27 Mar 2014 and first published online on 27 Mar 2014


Article type: Paper
DOI: 10.1039/C4DT00281D
Citation: Dalton Trans., 2014,43, 7522-7532
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    Thioether-ligated iron(II) and iron(III)-hydroperoxo/alkylperoxo complexes with an H-bond donor in the second coordination sphere

    L. R. Widger, Y. Jiang, A. C. McQuilken, T. Yang, M. A. Siegler, H. Matsumura, P. Moënne-Loccoz, D. Kumar, S. P. de Visser and D. P. Goldberg, Dalton Trans., 2014, 43, 7522
    DOI: 10.1039/C4DT00281D

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