Jump to main content
Jump to site search

Issue 14, 2014
Previous Article Next Article

A mixed valent heterometallic CuII/NaI coordination polymer with sodium–phenyl bonds

Author affiliations

Abstract

A mixed valent heterometallic CuII/NaI coordination polymer (1) is generated by the reaction of a Schiff base ligand, (6,6′-(1E,1′E)-(2-hydroxypropane-1,3-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2-methoxyphenol)) with copper(II) acetate and sodium perchlorate. In addition to the presence of alcohol oxygen–sodium coordination bonds, the single crystal X-ray structure reveals that the 1D coordination polymer is stabilised by the formation of phenyl–sodium η2-bonds, face-to-face π–π contacts and Cu–π interactions.

Graphical abstract: A mixed valent heterometallic CuII/NaI coordination polymer with sodium–phenyl bonds

Back to tab navigation

Supplementary files

Publication details

The article was received on 20 Jan 2014, accepted on 03 Feb 2014 and first published on 06 Feb 2014


Article type: Paper
DOI: 10.1039/C4DT00189C
Author version available: Download Author version (PDF)
Citation: Dalton Trans., 2014,43, 5558-5563
  •   Request permissions

    A mixed valent heterometallic CuII/NaI coordination polymer with sodium–phenyl bonds

    A. Datta, K. Das, C. Massera, J. K. Clegg, C. Sinha, J. Huang and E. Garribba, Dalton Trans., 2014, 43, 5558
    DOI: 10.1039/C4DT00189C

Search articles by author

Spotlight

Advertisements