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Issue 19, 2014
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A highly selective and sensitive Zn(II) complex-based chemosensor for sequential recognition of Cu(II) and cyanide

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Abstract

Two new Schiff base complexes, [ZnL(Ac)]2 (1) and [CuLCl]·H2O (2) (HL = 2-(2′-hydroxynaphthylmethylene)aminophenylbenzimidazole, Ac = acetate) were synthesized by a one-pot reaction and characterized by elemental analyses, IR and single-crystal X-ray diffraction. Fluorescence of complex 1 showed “on–off–on” switching when Cu2+ and cyanide were sequentially detected. This phenomenon was investigated by UV-Vis absorption, fluorescence and ESI-MS spectra, and theoretical calculations to explain the response. Complex 1 can selectively respond to Cu2+ with the fluorescence “turn-off” owing to the formation of complex 2 in the solution. Interestingly, the quenched fluorescence of complex 1 by Cu2+ ions could be turned on after the addition of cyanide owing to the displacement of L by CN to form [Cu(CN)x]n, making complex 1 a selective CN probe. In addition, the results of the MTT assay experiment indicate that complex 1 has a low toxicity to cells and can be used to detect intracellular Cu2+ ion by live cell imaging.

Graphical abstract: A highly selective and sensitive Zn(ii) complex-based chemosensor for sequential recognition of Cu(ii) and cyanide

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Publication details

The article was received on 29 Dec 2013, accepted on 21 Feb 2014 and first published on 21 Feb 2014


Article type: Paper
DOI: 10.1039/C3DT53647E
Citation: Dalton Trans., 2014,43, 7298-7303
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    A highly selective and sensitive Zn(II) complex-based chemosensor for sequential recognition of Cu(II) and cyanide

    W. Cao, X. Zheng, D. Fang and L. Jin, Dalton Trans., 2014, 43, 7298
    DOI: 10.1039/C3DT53647E

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