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Issue 13, 2014
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A multinuclear 1H, 13C and 11B solid-state MAS NMR study of 16- and 18-electron organometallic ruthenium and osmium carborane complexes

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Abstract

The first 1H, 13C, 31P and 11B solid state MAS NMR studies of electron-deficient carborane-containing ruthenium and osmium complexes [Ru/Os(p-cym)(1,2-dicarba-closo-dodecaborane-1,2-dithiolate)] are reported. The MAS NMR data from these 16-electron complexes are compared to those of free carborane-ligand and an 18-electron triphenylphosphine ruthenium adduct, and reveal clear spectral differences between 16- and 18-electron organometallic carborane systems in the solid state.

Graphical abstract: A multinuclear 1H, 13C and 11B solid-state MAS NMR study of 16- and 18-electron organometallic ruthenium and osmium carborane complexes

  • This article is part of the themed collection: Carboranes
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Publication details

The article was received on 20 Dec 2013, accepted on 12 Feb 2014 and first published on 20 Feb 2014


Article type: Communication
DOI: 10.1039/C3DT53589D
Citation: Dalton Trans., 2014,43, 4945-4949
  • Open access: Creative Commons BY license
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    A multinuclear 1H, 13C and 11B solid-state MAS NMR study of 16- and 18-electron organometallic ruthenium and osmium carborane complexes

    N. P. E. Barry, T. F. Kemp, P. J. Sadler and J. V. Hanna, Dalton Trans., 2014, 43, 4945
    DOI: 10.1039/C3DT53589D

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