Issue 16, 2014
From the journal:

Dalton Transactions

Reactivity of gold nanoparticles towards N-heterocyclic carbenes†

María Rodríguez-Castillo,a   Danielle Laurencin,a   Frederik Tielens,b   Arie van der Lee,c   Sébastien Clément,a   Yannick Guaria  and  Sébastien Richeter*a  

* Corresponding authors

a Institut Charles Gerhardt Montpellier ICGM, UMR5253 CNRS-ENSCM-UM2-UM1, Place E. Bataillon, 34095 Montpellier Cedex 05, France
E-mail: sricheter@univ-montp2.fr
Fax: +33 4 6714 3852
Tel: +33 4 6714 3971

b UPMC Université Paris 06, UMR 7574, Laboratoire Chimie de la Matière Condensée de Paris, Collège de France, 11 place M. Berthelot, 75231 Paris Cedex 05, France

c Institut Européen des Membranes, UMR 5635, CNRS, UM2, ENSCM, CC047, Place E. Bataillon, 34095 Montpellier Cedex 05, France

Abstract

The reaction of gold nanoparticles with benzimididazol-2-ylidene ligands leads to the formation of well-defined bis-carbene gold(I) complexes, as shown by characterization techniques such as powder XRD and solid state NMR.

Graphical abstract: Reactivity of gold nanoparticles towards N-heterocyclic carbenes

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Article information

DOI
https://doi.org/10.1039/C3DT53579G
Article type
Communication
Submitted
20 Dec 2013
Accepted
06 Jan 2014
First published
07 Jan 2014

Dalton Trans., 2014,43, 5978-5982

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Reactivity of gold nanoparticles towards N-heterocyclic carbenes

M. Rodríguez-Castillo, D. Laurencin, F. Tielens, A. van der Lee, S. Clément, Y. Guari and S. Richeter, Dalton Trans., 2014, 43, 5978 DOI: 10.1039/C3DT53579G

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