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Issue 18, 2014
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New oligogermane with a five coordinate germanium atom: the preparation of 1-germylgermatrane

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Abstract

The first example of an oligogermane, N(CH2CH2O)3Ge–Ge(SiMe3)3 (1), containing a hypercoordinate germanium atom was prepared and characterized by various methods (NMR, UV/vis, and X-ray analysis). The electronic structure of compound 1 was investigated via DFT calculations.

Graphical abstract: New oligogermane with a five coordinate germanium atom: the preparation of 1-germylgermatrane

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Publication details

The article was received on 16 Dec 2013, accepted on 20 Jan 2014 and first published on 23 Jan 2014


Article type: Communication
DOI: 10.1039/C3DT53523A
Citation: Dalton Trans., 2014,43, 6605-6609
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    New oligogermane with a five coordinate germanium atom: the preparation of 1-germylgermatrane

    K. V. Zaitsev, A. V. Churakov, O. Kh. Poleshchuk, Y. F. Oprunenko, G. S. Zaitseva and S. S. Karlov, Dalton Trans., 2014, 43, 6605
    DOI: 10.1039/C3DT53523A

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