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Issue 10, 2014
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A novel manganese-doped large polyoxotitanate nanocluster

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Abstract

A large manganese-doped polyoxotitanate nanocluster Ti28MnO38(OEt)40H2, has been synthesized solvothermally. Its structure is arranged around the four-coordinate Mn2+ dopant atom in a Keggin-type structure. A significant reduction of the band gap relative to that of undoped polyoxotitanate clusters is observed.

Graphical abstract: A novel manganese-doped large polyoxotitanate nanocluster

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Publication details

The article was received on 04 Dec 2013, accepted on 14 Jan 2014 and first published on 15 Jan 2014


Article type: Communication
DOI: 10.1039/C3DT53416B
Citation: Dalton Trans., 2014,43, 3839-3841
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    A novel manganese-doped large polyoxotitanate nanocluster

    Y. Chen, E. Trzop, A. Makal, Y. Chen and P. Coppens, Dalton Trans., 2014, 43, 3839
    DOI: 10.1039/C3DT53416B

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