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Issue 8, 2014
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Efficient synthesis of manganese(II) carboxylates: from a trinuclear cluster [Mn3(PhCO2)6(THF)4] to a unique [Mn(PhCO2)2]n chiral 3D network

Arkadiusz Kornowicz,a  Szymon Komorski,a  Zbigniew Wróbel,b  Iwona Justyniak,b  Natalia Nedelko,c  Anna Ślawska-Waniewska,c  Robert Balawenderb  and  Janusz Lewiński*ab 
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* Corresponding authors

a Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland
E-mail: lewin@ch.pw.edu.pl
Web: http://lewin.ch.pw.edu.pl
Fax: (+)48-22-234-7279

b Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland

c Institute of Physics, Polish Academy of Sciences, al. Lotników 32/46, Warszawa 02-668, Poland

Abstract

An efficient synthetic procedure for obtaining manganese carboxylates including a trinuclear cluster [Mn3(PhCO2)6(THF)4]2 and a unique [Mn(PhCO2)2]n chiral 3D network is reported. The procedure involves a simple redox process, in which acidic protons are reduced to gaseous hydrogen by oxidizing metallic manganese under solvothermal conditions.

Graphical abstract: Efficient synthesis of manganese(ii) carboxylates: from a trinuclear cluster [Mn3(PhCO2)6(THF)4] to a unique [Mn(PhCO2)2]n chiral 3D network

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Publication details

The article was received on 12 Sep 2013, accepted on 14 Nov 2013 and first published on 14 Nov 2013


Article type: Communication
DOI: 10.1039/C3DT53211A
Author version available: Download Author version (PDF)
Citation: Dalton Trans., 2014,43, 3048-3051
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    Efficient synthesis of manganese(II) carboxylates: from a trinuclear cluster [Mn3(PhCO2)6(THF)4] to a unique [Mn(PhCO2)2]n chiral 3D network

    A. Kornowicz, S. Komorski, Z. Wróbel, I. Justyniak, N. Nedelko, A. Ślawska-Waniewska, R. Balawender and J. Lewiński, Dalton Trans., 2014, 43, 3048
    DOI: 10.1039/C3DT53211A

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