Issue 11, 2014

Reactivity of three-coordinate iron–NHC complexes towards phenylselenol and lithium phenylselenide

Abstract

The three-coordinate iron(II) NHC complexes [(IPr)Fe(N′′)2] (1) and [(ItBu)Fe(N′′)2] (3) (N′′ = N(SiMe3)2) react with PhSeH or LiSePh to give the iron(II) selenolates [(IPr)Fe(N′′)(SePh)] (6) and [ItBu(H)][(aItBu)Fe(SePh)3], [ItBu(H)][7], with complex 7 containing an abnormal NHC ligand.

Graphical abstract: Reactivity of three-coordinate iron–NHC complexes towards phenylselenol and lithium phenylselenide

Supplementary files

Article information

Article type
Communication
Submitted
13 Nov 2013
Accepted
27 Nov 2013
First published
02 Dec 2013

Dalton Trans., 2014,43, 4251-4254

Reactivity of three-coordinate iron–NHC complexes towards phenylselenol and lithium phenylselenide

T. Pugh and R. A. Layfield, Dalton Trans., 2014, 43, 4251 DOI: 10.1039/C3DT53203H

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