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Issue 14, 2014
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Exceptional temperature-dependent coordination sites from acylamide groups

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Abstract

Herein, through altering the reaction temperature, the coordination mode of the acylamide ligand is well controlled with or without the oxygen coordination site. The resulting two new coordination polymers have the formulas Cd3(L)2(bdc)3·4(H2O) (1) and Cd(L)(bdc)·2(H2O) (2) (L = N1,N4-bis(pyridin-3-ylmethyl)terephthalamide, H2bdc = terephthalic acid).

Graphical abstract: Exceptional temperature-dependent coordination sites from acylamide groups

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Publication details

The article was received on 05 Nov 2013, accepted on 03 Jan 2014 and first published on 06 Jan 2014


Article type: Communication
DOI: 10.1039/C3DT53123F
Citation: Dalton Trans., 2014,43, 5260-5264
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    Exceptional temperature-dependent coordination sites from acylamide groups

    S. Huang, J. Li, J. Li, W. Xu, M. Luo, Y. Zhu and F. Luo, Dalton Trans., 2014, 43, 5260
    DOI: 10.1039/C3DT53123F

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