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Issue 14, 2014
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Oxacalix[4]arene-supported di-, tetra- and undecanuclear copper(II) clusters

Robyn E. Fairbairn,a  Ross McLellan,a  Ruaraidh D. McIntosh,a  Maria A. Palacios,b  Euan K. Brechin*b  and  Scott J. Dalgarno*a 
Author affiliations

* Corresponding authors

a Institute of Chemical Sciences, Heriot-Watt University, Riccarton, Edinburgh, UK
E-mail: S.J.Dalgarno@hw.ac.uk
Fax: +44(0)131 451 3180
Tel: +44(0)131 451 8025

b EaStCHEM School of Chemistry, University of Edinburgh, West Mains Road, Edinburgh, UK
E-mail: ebrechin@staffmail.ed.ac.uk
Fax: +44(0)131 650 6453
Tel: +44(0)131 650 7545

Abstract

Oxacalix[4]arenes containing either one or two oxa-bridges afford di and undecanuclear CuII clusters respectively upon reaction with cupric nitrate under facile conditions. Variation in reaction conditions results in formation of a tetranuclear CuII cluster with mono-oxacalix[4]arene, representing a structural expansion of the dinuclear assembly.

Graphical abstract: Oxacalix[4]arene-supported di-, tetra- and undecanuclear copper(ii) clusters

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Publication details

The article was received on 31 Oct 2013, accepted on 04 Dec 2013 and first published on 12 Dec 2013


Article type: Paper
DOI: 10.1039/C3DT53088D
Citation: Dalton Trans., 2014,43, 5292-5298
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    Oxacalix[4]arene-supported di-, tetra- and undecanuclear copper(II) clusters

    R. E. Fairbairn, R. McLellan, R. D. McIntosh, M. A. Palacios, E. K. Brechin and S. J. Dalgarno, Dalton Trans., 2014, 43, 5292
    DOI: 10.1039/C3DT53088D

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