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Issue 1, 2014
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Impact of high π-density on the coordination properties of π-excess aromatic neutral σ2P ligands – P(π)-donor bonds to Ag+ and HgCl2

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Abstract

Unprecedented coordination types of non-zerovalent d10 transition metals (AgX, HgCl2) by π-excess aromatic P[double bond, length as m-dash]C ligands involving P(π)-donor bond contributions were detected by structural and quantum chemical studies.

Graphical abstract: Impact of high π-density on the coordination properties of π-excess aromatic neutral σ2P ligands – P(π)-donor bonds to Ag+ and HgCl2

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Publication details

The article was received on 15 Oct 2013, accepted on 17 Oct 2013 and first published on 22 Oct 2013


Article type: Communication
DOI: 10.1039/C3DT52909F
Citation: Dalton Trans., 2014,43, 51-54
  • Open access: Creative Commons BY license
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    Impact of high π-density on the coordination properties of π-excess aromatic neutral σ2P ligands – P(π)-donor bonds to Ag+ and HgCl2

    M. Ghalib, L. Könczöl, L. Nyulászi, P. G. Jones, G. J. Palm and J. W. Heinicke, Dalton Trans., 2014, 43, 51
    DOI: 10.1039/C3DT52909F

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