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Issue 8, 2014
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A semi-flexible aminotriazine-based bis-methylpyridine ligand for the design of nickel(II) spin clusters

Yen-Wen Tzeng,a  Chang-Jui Lin,a  Motohiro Nakano,b  Chen-I Yang,*a  Wun-Long Wanc  and  Long-Li Lai*c 
Author affiliations

* Corresponding authors

a Department of Chemistry, Tunghai University, Taichung 407, Taiwan
E-mail: ciyang@thu.edu.tw
Fax: +886-4-23590426

b Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Japan

c Department of Applied Chemistry, National Chi Nan University, Nantou 545, Taiwan
E-mail: lilai@ncnu.edu.tw

Abstract

The self-assembly of a semi-flexible aminotriazine-based bis-methylpyridine ligand, N2,N2-dibenzyl-N4,N6-di(pyridylmethyl)-1,3,5-triazine-2,4,6-triamine (H2L), with NiCl2 and NiBr2 afforded two new nickel(II) clusters, (H2NMe2)2[Ni5(OH)2(H2L)2Cl10] (1) and [Ni6(OH)2(H2L)2Br10(THF)2] (2) showing a high spin ground state of S = 3.

Graphical abstract: A semi-flexible aminotriazine-based bis-methylpyridine ligand for the design of nickel(ii) spin clusters

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Publication details

The article was received on 15 Oct 2013, accepted on 30 Oct 2013 and first published on 05 Nov 2013


Article type: Communication
DOI: 10.1039/C3DT52903G
Citation: Dalton Trans., 2014,43, 3044-3047
  • Open access: Creative Commons BY license
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    A semi-flexible aminotriazine-based bis-methylpyridine ligand for the design of nickel(II) spin clusters

    Y. Tzeng, C. Lin, M. Nakano, C. Yang, W. Wan and L. Lai, Dalton Trans., 2014, 43, 3044
    DOI: 10.1039/C3DT52903G

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