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Issue 5, 2014
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Molecular tectonics: homochiral coordination networks based on combinations of a chiral neutral tecton with Hg(II), Cu(II) or Ni(II) neutral complexes as metallatectons

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Abstract

The use of compound 1 as an enantiomerically pure neutral and rigid organic linear tecton bearing two divergently oriented monodentate coordinating sites appended with two chiral centres of the same (S) configuration leads, in the presence of neutral metal complexes behaving either as a linear (Cu(hfac)2, Cu(OAc)2) or a V-shaped (HgCl2) 2-connecting node or a 4-connecting square node (NiCl2), to the formation of four homochiral 1- and 2-D coordination polymers.

Graphical abstract: Molecular tectonics: homochiral coordination networks based on combinations of a chiral neutral tecton with Hg(ii), Cu(ii) or Ni(ii) neutral complexes as metallatectons

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Publication details

The article was received on 10 Oct 2013, accepted on 05 Nov 2013 and first published on 05 Nov 2013


Article type: Paper
DOI: 10.1039/C3DT52850B
Citation: Dalton Trans., 2014,43, 2000-2006
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    Molecular tectonics: homochiral coordination networks based on combinations of a chiral neutral tecton with Hg(II), Cu(II) or Ni(II) neutral complexes as metallatectons

    P. Larpent, A. Jouaiti, N. Kyritsakas and M. W. Hosseini, Dalton Trans., 2014, 43, 2000
    DOI: 10.1039/C3DT52850B

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