Issue 2, 2014
From the journal:

Dalton Transactions

Synthesis, structure and spectroscopic analyses of aquachloridooxidodiperoxidomolybdate(vi)†‡

Masa-aki Saitoa  and  Masato Hashimoto*a  

* Corresponding authors

a Department of Material Science and Chemistry, Faculty of Systems Engineering, Wakayama University, Sakaedani 930, Wakayama 640 8510, Japan
E-mail: mh1043@center.wakayama-u.ac.jp
Fax: +81 73 457 8259
Tel: +81 73 457 8258

Abstract

A novel aquachloridooxidodiperoxidomolybdate(VI), [MoClO(O2)2(OH2)]−, was crystallised as tetraethylammonium and triethylmethylammonium salts from strongly acidic aqueous solutions, and was structurally analysed by single crystal X-ray diffraction and NMR spectroscopy. The aqueous behaviour of the present anion observed by 17O NMR agrees with that reported in a previous speciation study.

Graphical abstract: Synthesis, structure and spectroscopic analyses of aquachloridooxidodiperoxidomolybdate(vi)

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3DT52848K
Article type
Communication
Submitted
10 Oct 2013
Accepted
26 Oct 2013
First published
29 Oct 2013

Dalton Trans., 2014,43, 402-405

Permissions

Request permissions

Synthesis, structure and spectroscopic analyses of aquachloridooxidodiperoxidomolybdate(VI)

M. Saito and M. Hashimoto, Dalton Trans., 2014, 43, 402 DOI: 10.1039/C3DT52848K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements