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Crystal structures and DFT calculations of new chlorido-dimethylsulfoxide-MIII (M = Ir, Ru, Rh) complexes with the N-pyrazolyl pyrimidine donor ligand: kinetic vs. thermodynamic isomers

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a
Departament de Química, Universitat de les Illes Balears, Crta. de Valldemossa km 7.5, 07122 Palma de Mallorca (Balears), Spain
E-mail: toni.frontera@uib.es
b
Institute of Chemical Research of Catalonia (ICIQ), Avgda. Països Catalans 16, 43007 Tarragona, Spain
c
Catalan Institution for Research and Advanced Studies (ICREA), Passeig Lluís Companys, 23, Barcelona, Spain
d
Institut de Ciència de Materials de Barcelona (CSIC), Campus UAB, 08193 Bellaterra, Spain
e
Department of Chemistry (Nanoscience and Nanotechnology), University of Delhi (North Campus), Delhi-110 007, India
Dalton Trans., 2014,43, 6353-6364

DOI: 10.1039/C3DT52700J
Received 27 Sep 2013, Accepted 03 Feb 2014
First published online 03 Feb 2014
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