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Issue 8, 2014
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Lanthanide complexes with aromatic o-phosphorylated ligands: synthesis, structure elucidation and photophysical properties

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Abstract

Lanthanide complexes LnL3 (Ln = Sm, Eu, Tb, Dy, Tm, Yb, Lu) with aromatic o-phosphorylated ligands (HL1 and HL2) have been synthesized and identified. Their molecular structure was proposed on the basis of a new complex approach, including DFT calculations, Sparkle/PM3 modelling, EXAFS spectroscopy and luminescent probing. The photophysical properties of all of the complexes were investigated in detail to obtain a deeper insight into the energy transfer processes.

Graphical abstract: Lanthanide complexes with aromatic o-phosphorylated ligands: synthesis, structure elucidation and photophysical properties

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Publication details

The article was received on 20 Sep 2013, accepted on 18 Oct 2013 and first published on 24 Oct 2013


Article type: Paper
DOI: 10.1039/C3DT52600C
Citation: Dalton Trans., 2014,43, 3121-3136
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    Lanthanide complexes with aromatic o-phosphorylated ligands: synthesis, structure elucidation and photophysical properties

    S. Shuvaev, V. Utochnikova, Ł. Marciniak, A. Freidzon, I. Sinev, R. Van Deun, R. O. Freire, Y. Zubavichus, W. Grünert and N. Kuzmina, Dalton Trans., 2014, 43, 3121
    DOI: 10.1039/C3DT52600C

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