Jump to main content
Jump to site search

Issue 15, 2014
Previous Article Next Article

Novel tandem synthesis of bis(μ-NN′-tetrazolate) bridged dinuclear nickel(II) Schiff base complex via [3 + 2] cyclo-addition at ambient condition

Author affiliations

Abstract

A novel bis(μ-NN′-tetrazolate) bridged centrosymmetric dinuclear nickel(II) Schiff base complex [Ni2(L)2(PTZ)2]·2H2O·2CH3CN (HL is a tridentate Schiff base, 2-((2-(ethylamino)ethylimino)methyl)-6-methoxyphenol and HPTZ is 5-pyrazinyltetrazole) has been synthesized via [3 + 2] cyclo-addition reaction of 2-cyanopyrazine and sodium azide in presence of nickel(II) acetate tetrahydrate and HL. The structure of the complex is confirmed by single crystal X-ray diffraction analysis. The combination of H-bonding and C–H⋯π interactions creates a 36-hxl topological supramolecular network. The acetonitrile molecules are encapsulated as a hydrophobic guest within the 2D supramolecular network.

Graphical abstract: Novel tandem synthesis of bis(μ-NN′-tetrazolate) bridged dinuclear nickel(ii) Schiff base complex via [3 + 2] cyclo-addition at ambient condition

Back to tab navigation

Supplementary files

Publication details

The article was received on 02 Sep 2013, accepted on 06 Jan 2014 and first published on 07 Jan 2014


Article type: Communication
DOI: 10.1039/C3DT52398E
Citation: Dalton Trans., 2014,43, 5643-5647
  •   Request permissions

    Novel tandem synthesis of bis(μ-NN′-tetrazolate) bridged dinuclear nickel(II) Schiff base complex via [3 + 2] cyclo-addition at ambient condition

    M. Das, K. Harms and S. Chattopadhyay, Dalton Trans., 2014, 43, 5643
    DOI: 10.1039/C3DT52398E

Search articles by author

Spotlight

Advertisements