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Issue 4, 2014
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A new polymorph of lithium manganese(II) pyrophosphate β-Li2MnP2O7

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Abstract

A new polymorph of lithium manganese pyrophosphate was synthesized by low-temperature solid-state synthesis, and the crystal structure was determined. The new phase has a new type of three-dimensional framework structure, which is completely different from that found in the previous study by Adam et al., J. Solid State Chem., 2008, 181, 3110. Electrochemical measurement with a Li cell demonstrated a reversible electrochemical activity at around 4 V.

Graphical abstract: A new polymorph of lithium manganese(ii) pyrophosphate β-Li2MnP2O7

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Publication details

The article was received on 27 Aug 2013, accepted on 06 Nov 2013 and first published on 08 Nov 2013


Article type: Communication
DOI: 10.1039/C3DT52347K
Citation: Dalton Trans., 2014,43, 1502-1504
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    A new polymorph of lithium manganese(II) pyrophosphate β-Li2MnP2O7

    S. Nishimura, R. Natsui and A. Yamada, Dalton Trans., 2014, 43, 1502
    DOI: 10.1039/C3DT52347K

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