Jump to main content
Jump to site search

Issue 2, 2014
Previous Article Next Article

Syntheses, structures and properties of two 2-D layered hybrid organic–inorganic materials based on different V4O12 building units

Author affiliations

Abstract

Two new layered hybrid organic–inorganic compounds [Zn(pyim)]2V4O12 (1) (pyim = 2-(2-pyridyl)imidazole) and [Cu(bim)2]2V4O12(H2O)·CH3CH2OH (2) (bim = bis(1-imidazolyl)methane) based on polyoxovanadates (POVs) and organic ligands decorated transition metal units have been synthesized by hydrothermal and solvothermal methods respectively. Single crystal XRD, fluorescence spectrum, magnetic measurement, IR spectra, powder XRD and thermogravimetric (TG) measurements were performed to analyze the structures and properties of 1 and 2. The structural analysis reveals that compound 1 features a two-dimensional {[Zn(pyim)]2V4O12}n layered structure, constructed by sine wave-like {V4O12}n4n chains, Zn2+ ions and pyim ligands. In the layered structure of 2, {V4O12}4− circles are connected by Cu2+ ions to form {Cu(V4O12)}n2n chains, which are further linked by {Cu(bim)4}2+ subunits to generate a hybrid layer of 2. The magnetic susceptibility measurement indicates strong antiferromagnetic interactions between Cu2+ ions in 2.

Graphical abstract: Syntheses, structures and properties of two 2-D layered hybrid organic–inorganic materials based on different V4O12 building units

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 12 Aug 2013, accepted on 25 Sep 2013, published on 30 Sep 2013 and first published online on 30 Sep 2013


Article type: Paper
DOI: 10.1039/C3DT52195H
Citation: Dalton Trans., 2014,43, 865-871
  •   Request permissions

    Syntheses, structures and properties of two 2-D layered hybrid organic–inorganic materials based on different V4O12 building units

    W. Hou, J. Guo, X. Xu, Z. Wang, D. Zhang, H. Wan, Y. Song, D. Zhu and Y. Xu, Dalton Trans., 2014, 43, 865
    DOI: 10.1039/C3DT52195H

Search articles by author