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Structural diversity and spectral and thermal properties of the first alkaline earth metal tetracyanidoborates: [Mg(H2O)6][B(CN)4]2, [Mg(H2O)2][B(CN)4]2, [Mg(DMF)6][B(CN)4]2, [Ca(H2O)3][B(CN)4]2, and [Ca(H2O)2(CH3CN)][B(CN)4]2

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a
Institut für Chemie, Anorganische Chemie/Festkörperchemie, Universität Rostock, Albert-Einstein-Str 3a, D-18059 Rostock, Germany
E-mail: Martin.Koeckerling@uni-rostock.de;
Fax: +49 (0)381 498 6382 ;
Tel: +49 (0)381 498 6390
b
FB C – Anorganische Chemie, Bergische Universität Wuppertal, Gaußstraße 20, D-42119 Wuppertal, Germany
E-mail: edbern@uni-wuppertal.de;
Fax: +49(0)202 439 3053 ;
Tel: +49(0)202 439 2502
Dalton Trans., 2014,43, 7128-7138

DOI: 10.1039/C3DT51945G
Received 17 Jul 2013, Accepted 24 Feb 2014
First published online 25 Feb 2014
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